Supramolecular Gold(I) Thiobarbiturate Chemistry: Combining Aurophilicity and Hydrogen Bonding to Make Polymers, Sheets, and Networks

The cooperative forces of aurophilic and hydrogen bonding have been used in the self-assembly of phosphine or
diphosphine complexes of gold(I) with the thiolate ligands derived from 2-thiobarbituric acid, SC4H4N2O2, by single
or double deprotonation. The reaction of the corresponding gold(I) trifluoroacetate complex with SC4H4N2O2 gave
the complexes [Au(SC4H3N2O2)(PPh3)], 1, [(AuSC4H3N2O2)2(μ-LL)], with LL = Ph2PCH2PPh2, 2a, Ph2P(CH2)3PPh2,
2b, or Ph2PCHCHPPh2, 2c, or the cyclic complex [Au2(μ-SC4H2N2O2)(μ-Ph2PCH2CH2PPh2)], 3. In the case with
LL = Ph2P(CH2)6PPh2, the reaction led to loss of the diphosphine ligand to give [Au6(SC4H3N2O2)6], 4, a hexagold(I)
cluster complex in which each gold(I) center has trigonal AuS2N coordination. Structure determinations show that
1 has no aurophilic bonding, 2b, 3, and 4 have intramolecular aurophilic bonding, and 2c has intermolecular
aurophilic bonding that contributes to the supramolecular structure. All the complexes undergo supramolecular
association through strong NH···O and/or OH···N hydrogen bonding, and complex 3 also takes part in CH···O
hydrogen bonding. The supramolecular association leads to formation of interesting polymer, sheet, or network
structures, and 4 has a highly porous and stable lattice structure.