Reactions of 9-Triptyceneselenol with Palladium(0) Complexes: Unexpected Formations of the Dinuclear Palladium(I) Complex [{Pd(PPh<sub>3</sub>)}<sub>2</sub>(μ-SeTrip)<sub>2</sub>] and Five-Membered Selenapalladacycle [Pd(η<sup>2</sup>(<i>C</i>,<i>Se</i>)-Trip)(dppe)]
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The oxidative addition reaction of the overcrowded selenol TripSeH (1; Trip = 9-triptycyl) with [Pd(Ph3P)4] in toluene produced a novel dinuclear palladium(I) complex with bridging selenolato ligands, [{Pd(PPh3)}2(μ-SeTrip)2] (2). In contrast, the reaction of 1 with [Pd(dppe)2] in toluene resulted in the formation of the five-membered selenapalladacycle [Pd(η2(C,Se)-Trip)(dppe)] (3).
创建时间：
2009-04-13
