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Novel Approach to Multimetal Metallaborane Clusters. Synthesis of Hypoelectronic <i>n</i><i>ido-</i>Cp*<sub>3</sub>IrRu<sub>2</sub>B<sub>5</sub>H<sub>9</sub> from the Reaction of <i>a</i><i>rachno-</i>Cp*IrB<sub>3</sub>H<sub>9</sub> with <i>n</i><i>ido-</i>(Cp*RuH)<sub>2</sub>B<sub>3</sub>H<sub>7</sub>

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Two new mixed-metal metallaborane clusters, Cp*3Ru2IrB5H9 and Cp*3Ru2IrB5H5, were isolated from the reaction of an iridaborane with a ruthenaborane. The structures show the former to have an unusual nido eight-atom cluster shape with a low electron count and the latter to have the expected bicapped-octahedral geometry.

创建时间:
2016-03-01
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