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Total Synthesis of (±)-Spiniferin-1 via a Polyfluoroalkanosulfonyl Fluoride Induced Homoallylic Carbocation Rearrangement Reaction

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Total_Synthesis_of_Spiniferin_1_via_a_Polyfluoroalkanosulfonyl_Fluoride_Induced_Homoallylic_Carbocation_Rearrangement_Reaction/2686600
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资源简介:
A facile total synthesis of marine natural product (±)-spiniferin-1 has been accomplished in eight steps with 28.9% overall yield, involving a rearrangement reaction initiated by polyfluoroalkanosulfonyl fluoride to construct the 1,6-methano[10]annulene core of the natural product as a key step.
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2016-02-23
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