Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center
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https://figshare.com/articles/dataset/Silver_Catalyzed_Long_Distance_Aryl_Migration_from_Carbon_Center_to_Nitrogen_Center/2105044
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资源简介:
Selective cleavage of an inert C–C
bond followed by C–O/N
bond formation through a long-distance aryl migration from a carbon
to a nitrogen center via Ag catalysis is reported. The migration products
were easily converted into γ-hydroxy amines and tetrahydroquinoline
derivatives in quantitative yields. Preliminary mechanistic studies
indicated a radical pathway.
创建时间:
2016-02-12



