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Pyridyl-Directed Cp*Rh(III)-Catalyzed B(3)–H Acyloxylation of <i>o</i>‑Carborane

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NIAID Data Ecosystem2026-03-10 收录
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An efficient pyridyl-directed Rh­(III)-catalyzed o-carborane B­(3)–H acyloxylation is reported. The B(3)–H bond is the most electron-deficient vertex on o-carborane whose functionalization is challenging. The combination of Cu­(OH)2 and diverse carboxylic acids provides low cost and abundant acyloxyl sources which could lead to moderate to excellent yields.

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2017-09-20
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