Hindered Rotation Leading to Nonequivalence in Cobaloximes
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The cobalt-bound CH2 becomes diastereotopic and the dmgH methyl protons show nonequivalence at subzero temperature in benzylcobaloximes. The interaction of axial with equatorial ligands causes hindered rotation of the Co−C and/or C−Ph bond and leads to nonequivalence.
创建时间：
2016-03-01
