Chiral Synthesis of McGeachin-Type Bisaminals
收藏NIAID Data Ecosystem2026-03-11 收录
下载链接：
https://figshare.com/articles/dataset/Chiral_Synthesis_of_McGeachin-Type_Bisaminals/11845002
下载链接
链接失效反馈官方服务：
资源简介：
Bridged [3.3.1]-bisaminal structures,
namely 6,12-epiminodibenzo[b,f][1,5]diazocines,
are herein named McGeachin-type
bisaminals. The TsOH-catalyzed chiral synthesis of McGeachin-type
bisaminals is first developed by condensation of two molecules of
2-(methylamino)benzaldehyde and one molecule of chiral amines. Two
chiral diastereomers are generated simultaneously and are isolated
by column chromatography in a total yield of up to 99%. The absolute
structure of one stereoisomer was determined by X-ray crystallography.
创建时间：
2020-01-30
