Observation of Hysteretic Bistability in [Co<sup>III</sup>Cp<sub>2</sub>]<sup>+</sup>[Fe<sup>III</sup>I<sub>4</sub>]<sup>-</sup>
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[CoIIICp2]+[FeIIII4]- (Cp = cyclopentadienyl) prepared by the double oxidation of FeI2 and CoCp2 with iodine exhibits a 30 °C thermal hysteresis in magnetic susceptibility between 134 and 164 K that is attributed to a phase transition to a disordered triclinic unit cell from an ordered monoclinic unit cell upon cooling.
创建时间:
2016-05-06



