Total Syntheses of (+)-α-Allokainic Acid and (−)-2-epi-α-Allokainic Acid Employing Ketopinic Amide as a Chiral Auxiliary
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Asymmetric Michael reaction of iminoglycinate 4 to α,β-unsaturated esters had been developed with >98:1 and (−)-2-epi-α-allokainic acid 6 each in 11 synthetic steps starting from 4 in 17.8 and 18.0% yields, respectively.
创建时间：
2018-08-14
