Microwave-Assisted Domino and Multicomponent Reactions with Cyclic Acylketenes: Expeditious Syntheses of Oxazinones and Oxazindiones
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https://figshare.com/articles/dataset/Microwave_Assisted_Domino_and_Multicomponent_Reactions_with_Cyclic_Acylketenes_Expeditious_Syntheses_of_Oxazinones_and_Oxazindiones/2805844
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资源简介:
The microwave-assisted Wolff rearrangement of cyclic 2-diazo-1,3-diketones in the presence of aldehydes and primary amines provides a straightforward access to functionalized bi- and pentacyclic oxazinones following an unprecedented three-component domino reaction. Alternatively, in the presence of acyl azides, an efficient Curtius/Wolff/hetero-Diels−Alder sequence allows the direct synthesis of oxazindiones.
创建时间:
2016-02-25



