Raw data for High Temperature Photochromism of Fe-Doped SrTiO3 Caused by UV Induced Bulk Stoichiometry Changes

In the following the raw data lying the foundation of the paper High Temperature Photochromism of Fe-Doped SrTiO3 Caused by UV Induced Bulk Stoichiometry Changes (Viernstein et al.) published in Advanced Functional Materials Vo. 29 Issue 23 (WILEY-VCH Verlag GmbH & Co. KGaA, Germany) in 2019 are described. They were obtained under the funding provided by Austrian Science Fund (FWF) (project F4509-N16, FOXSI) and the European Union`s Horizon 2020 research and innovation program under the grant agreement No. 824072 and consist of UV/VIS spectra, van der Pauw measurements, electrochemical impedance spectra, and laser ablation ICP-MS data.

The UV/VIS measurements were carried out in air, at 440 °C using a deuterium and a tungsten lamp (Edmund Optics Inc., Germany) as light source and an Ocean Optics QE6500 (Halma plc, England) as spectrometer. The data include background, I0 and I absorption measurements of Fe doped SrTiO3 (STO) single crystals before, during, and after illumination with UV light (365 nm). The data files are labeled for example as “UVvis_FeSTO_background_1” or ”UVvis_FeSTO_I_440C_UVon_90s”, to state the type auf measurement, temperature, and status of the experiment. In each of them the average of 30 spectra is given and each exhibits two columns, namely wavelength, and intensity.

The van der Pauw measurements were performed on two Keithley 20 multimeter and a 2410 1100 V source meter (Keithley Instruments, USA). They are labeled in the following way: “date_applied voltage_atmosphere_sample identification_temperature cycle_status of the measurement”. Each file consists out of a header giving time, cycle number, temperature (real and set) and six columns, t[s], (applied) U[V], (measured) I[A], R [Ohm], and two unnamed columns ((applied) U[V] and (measured) U [V]).

The electrochemical impedance spectra were obtained before, during, and after UV exposure, using an Electrochemical Test Station POT/GAL 30 V/2 A or a Novocontrol Alpha‐A high‐performance frequency analyzer, respectively (both Novocontrol Technologies GmbH & Co. KG, Germany). Each spectrum is named after the following description: “date_sample name_UVonoff_real temperature_atmosphere_spectra number”. A header with date, time, cycle number, and temperature followed by four columns, namely Freq [Hz], Re (real part of the impedance spectra), Im (imaginary part), Amp (amplitude), and Pha (phase) are given.

Laser ablation ICP-MS measurements were performed on a NWR213 laser ablation system (ESI; USA) and an iCAP Q ICP-MS (Thermo Fisher Scientific, Germany). The obtained data file is labeled as Iaser_ablation_ICP_MS_FeSTO and exhibits sample names, names of the measured masses (isotopes) and the obtained counts.