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Formation and Structures of Germanium(II) Aryloxo/Oxo Clusters

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https://figshare.com/articles/dataset/Formation_and_Structures_of_Germanium_II_Aryloxo_Oxo_Clusters/2835094
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The reaction of Ge[N(SiMe3)2]2 with a phenol lacking a substituent in one ortho position results in the formation of polynuclear clusters having terminal aryloxide ligands and bridging O atoms. Structures of this type have not been observed for germanium(II) aryloxides before, and the source of the bridging O atoms in these clusters was determined to be the phenol reactant.
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2016-02-26
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