Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible C–O Bond Formation
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https://figshare.com/articles/dataset/Mechanistic_Analysis_of_Gold_I_Catalyzed_Intramolecular_Allene_Hydroalkoxylation_Reveals_an_Off_Cycle_Bis_gold_Vinyl_Species_and_Reversible_C_O_Bond_Formation/2516542
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资源简介：
Mechanistic investigation of gold(I)-catalyzed intramolecular
allene
hydroalkoxylation established a mechanism involving rapid and reversible
C–O bond formation followed by turnover-limiting protodeauration
from a mono(gold) vinyl complex. This on-cycle pathway competes with
catalyst aggregation and formation of an off-cycle bis(gold) vinyl
complex.
创建时间：
2012-06-06
