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Synthesis of N,N‑Dioxopyridazines

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Figshare2017-08-24 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_i_N_i_i_N_i_Dioxopyridazines/5341003
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Despite many efforts, one of the smallest heterocycles containing two nitrogen atoms, pyridazine, could not be converted to its N,N-dioxide (see, however, Nakadate et al. Chem. Pharm. Bull. 1970, 18, 1211–1218). HOF·CH3CN, made easily from diluted fluorine, was able to accomplish this task in a fast reaction with good yields.
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2017-08-24
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