Reductive Carbonylation of Oxorhenium Hydrides Induced by Lewis Acids
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https://figshare.com/articles/dataset/Reductive_Carbonylation_of_Oxorhenium_Hydrides_Induced_by_Lewis_Acids/3593376
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Several oxorhenium hydride complexes with chelating diamidopyridine (DAP), diamidoamine (DAAm), and 2-mercaptoethyl sulfide (SSS) groups have been isolated and characterized. Adduct formation is observed when the DAP complex 1a is treated with the Lewis acid B(C6F5)3. However, treatment of 1a,b with B(C6F5)3 or BF3·OEt2 in the presence of CO results in reduction of the metal center by four electrons from Re(V) to Re(I).
创建时间：
2016-09-06
