Spontaneous Oxygenation of Siloxy‑N‑silylketenimines to α‑Ketoamides
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https://figshare.com/articles/dataset/Spontaneous_Oxygenation_of_Siloxy_i_N_i_silylketenimines_to_Ketoamides/3118054
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Siloxy-N-silylketenimines generated in situ from O-silyl cyanohydrins were converted to α-ketoamides by brief exposure to air or oxygen. Oxidation under extremely mild conditions can be explained by assuming the intermediacy of a 3-imino-1,2-dioxetane derivative generated via triplet–singlet intersystem crossing after the reaction of siloxy-N-silylketenimines with triplet oxygen.
创建时间：
2016-03-28
