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Delocalized Hypervalent Silyl Radical Supported by Amidinate and Imino Substituents

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Figshare2016-12-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Delocalized_Hypervalent_Silyl_Radical_Supported_by_Amidinate_and_Imino_Substituents/4496000
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The reaction of the amidinato silylsilylene with a functionalized diaminochlorosilyl substituent, [LSiSi­(Cl)­{(NtBu)2C­(H)­Ph}] (1; L = PhC­(NtBu)2), with ArNCNAr (Ar = 2,6-iPr2C6H3) in toluene afforded the delocalized hypervalent silyl radical [LSi•(μ-CNAr)2Si­{(NtBu)2C­(H)­Ph}] (2). It possesses a hypervalent silyl radical that delocalizes throughout the Si2C2 ring.
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2016-12-23
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