Interaction of a C–F Bond with the π-System of a CC Bond or “Head On” with a Proximate C–H Bond
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https://figshare.com/articles/dataset/Interaction_of_a_C_F_Bond_with_the_System_of_a_C_C_Bond_or_Head_On_with_a_Proximate_C_H_Bond/2553583
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资源简介：
We describe the synthesis and preliminary study of two
molecules,
in which a fluorine atom is positioned proximately above the π-orbitals
of a CC bond or else wherein a C–F bond interacts in
a “head on” fashion with a proximate C–H bond.
The spectroscopic characteristics of these unusual interactions are
documented, X-ray crystallographic analyses are reported, and theoretical
calculations are employed to support the observed spectroscopy.
创建时间：
2012-02-03
