Synthesis of Cage-Shaped Aluminum Aryloxides: Efficient Lewis Acid Catalyst for Stereoselective Glycosylation Driven by Flexible Shift of Four- to Five-Coordination
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https://figshare.com/articles/dataset/Synthesis_of_Cage-Shaped_Aluminum_Aryloxides_Efficient_Lewis_Acid_Catalyst_for_Stereoselective_Glycosylation_Driven_by_Flexible_Shift_of_Four-_to_Five-Coordination/9936512
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资源简介：
Monomeric
cage-shaped aluminum aryl oxides 1Al were
synthesized using tripodal triphenolic ligands. The Lewis acidity
and catalytic activity of the obtained 1Al·py were
investigated. The Lewis acidity of 1Al·py originates
from the flexible change in the coordination number of the aluminum
center, allowing the catalytic O-glycosylation to
occur with a high efficiency and an unusual stereoselectivity.
创建时间：
2019-10-01
