Organocatalytic Enantioselective Construction of Axially Chiral Sulfone-Containing Styrenes
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https://figshare.com/articles/dataset/Organocatalytic_Enantioselective_Construction_of_Axially_Chiral_Sulfone-Containing_Styrenes/6397034
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资源简介：
We describe herein
an organocatalytic enantioselective approach
for the construction of axially chiral sulfone-containing styrenes.
Various axially chiral sulfone-containing styrene compounds were prepared
with excellent enantioselectivities (up to >99% ee) and almost
complete E/Z selectivities (>99% E/Z). Furthermore, the axially chiral sulfone-containing
styrenes could be easily converted into phosphonic acid and S/P ligands,
which could be potentially used as organocatalysts or ligands in asymmetric
catalysis.
创建时间：
2018-05-31
