Formation of N2O from a Nickel Nitrosyl: Isolation of the cis-[N2O2]2– Intermediate
收藏Figshare2016-02-20 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Formation_of_N_sub_2_sub_O_from_a_Nickel_Nitrosyl_Isolation_of_the_i_cis_i_N_sub_2_sub_O_sub_2_sub_sup_2_sup_Intermediate/2512267
下载链接
链接失效反馈官方服务：
资源简介：
Addition of 2,2′-bipyridine (bipy) to [Ni(NO)(bipy)][PF6] (1) results in formation of a rare five-coordinate nickel nitrosyl [Ni(NO)(bipy)2][PF6] (2). This complex exhibits a bent NO– ligand in the solid state. On standing in acetonitrile, 2 furnishes the NO coupled product, [Ni(κ2-O2N2)(bipy)] (8) in moderate yield. Subsequent addition of 2 equiv of acetylacetone (H(acac)) to 8 results in formation of [Ni(acac)2(bipy)], N2O, and H2O. Preliminary mechanistic studies suggest that the N–N bond is formed via a bimetallic coupling reaction of two NO– ligands.
创建时间：
2016-02-20
