Conformationally Driven Two- and Three-Photon Cascade Processes in the Stereoselective Photorearrangement of Pyrroles
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https://figshare.com/articles/dataset/Conformationally_Driven_Two-_and_Three-Photon_Cascade_Processes_in_the_Stereoselective_Photorearrangement_of_Pyrroles/4107132
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资源简介:
A TBSO group has
been shown to exert a high degree of stereocontrol
during the two-photon photocycloaddition/rearrangement of N-butenylpyrroles to complex tricyclic aziridines. Moreover,
this and other bulky groups have been shown to change the outcome
of the reaction, promoting a new two-photon sequence to tricyclic
imines and an unprecedented stereoselective three-photon sequence
to azabicyclo[3.3.1]nonanes.
创建时间:
2016-10-31



