Cobalt-Catalyzed Ligand-Controlled Regioselective Hydroboration/Cyclization of 1,6-Enynes
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https://figshare.com/articles/dataset/Cobalt-Catalyzed_Ligand-Controlled_Regioselective_Hydroboration_Cyclization_of_1_6-Enynes/4535786
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资源简介：
A ligand-controlled
cobalt-catalyzed regioselective hydroboration/cyclization
of 1,6-enynes with HBPin was developed by switching the size of the
coordinated side arm to afford alkenylboronates and alkylboronates,
respectively. Gram-scale reactions could be easily conducted, which
is beneficial for further derivatizations. A primary mechanism was
proposed on the basis of substrate-controlled experiments and deuterium
experiments.
创建时间：
2017-01-10
