A metal−organic honeycomb-like 2D pillared-bilayer open framework has been constructed which shows dynamic sponge-like single-crystal-to-single-crystal transformation upon dehydration and rehydration.
Metal–organic frameworks featuring ligands with open chelating groups are versatile platforms for the preparation of a diverse set of heterogeneous catalysts through postsynthetic metalation. The crys
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Single-crystal-to-single-crystal (SCSC) breathing and guest exchange properties of a series of CoII metal–organic frameworks (MOFs) are reported. A new bis-pyridyl-bis-amide ligand, namely 4,4′-oxybis