Stepwise Synthesis and Magnetic Control of Trimetallic Magnets [Co<sub>2</sub>Ln(L)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>][Cr(CN)<sub>6</sub>]·<i>n</i>H<sub>2</sub>O (Ln = La, Gd; H<sub>2</sub>L = 2,6-Di(acetoacetyl)pyridine) with 3-D Pillared-Layer Structure
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Integration of mononuclear [Cr(CN)6]3- and preorganized trinuclear [Co2Ln(L)2]3+ complexes provides novel trimetallic magnets having a 3-D pillared-layer framework with an alternate array of 2-D layer extended by Cr(III)−CN−Co(II) linkages and Ln(III) ion. The overall magnetic nature can be systematically controlled by Ln(III) ions inserted between the 2-D ferromagnetic layers.
创建时间：
2006-12-27
