Multiple Insertion of a Silyl Vinyl Ether by (α-Diimine)PdMe<sup>+</sup> Species

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Multiple_Insertion_of_a_Silyl_Vinyl_Ether_by_Diimine_PdMe_sup_sup_Species/2911438 数据链接链接失效反馈

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Multiple Insertion of a Silyl Vinyl Ether by (α-Diimine)PdMe+ Species

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2016-02-27

Tantallacarborane Mediated Consecutive C–C and C–N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N‑Heterocycles

有机金属催化

杂环化合物构建

Reactions of tantallacarborane methyl complexes ([η1:η5-(Me2NCH2CH2)C2B9H10]TaMe3 (1) and [η1:η5-(MeOCH2CH2)C2B9H10]TaMe3 (8)) with alkyl isonitriles have been studied. Complex 1 reacted with 1 eq

Figshare2016-02-12 更新70

Selective Boryl Silyl Ether Formation in the Photoreaction of Bisboryloxide/Boroxine with Hydrosilane Catalyzed by a Transition-Metal Carbonyl Complex

有机金属催化

硼烷化合物合成

Selective B–O–Si bond formation was achieved in the reaction of bisboryloxide O(Bpin)2 (pin = (OCMe2)2)/boroxine (MeBO)3 system with tertiary silane R3SiH in the presence of stoichiometric water and

NIAID Data Ecosystem60

Data for: Mechanistic insight into the rhodium-catalyzed, P-directed selective C7 arylation of indoles: a DFT study

反应机理

有机金属催化

Cartesian coordinates for all the structures involved in the artical of "mechanistic insight into the rhodium-catalyzed, P-directed selective C7 arylation of indoles: a DFT study".

NIAID Data Ecosystem20

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

有机金属催化

反应机理

New experimental findings suggest partial revision of the currently accepted mechanism of the carbonyl hydrosilylation catalyzed by the iridium(III) pincer complex introduced by Brookhart. Employing

NIAID Data Ecosystem60

Activation of Epoxides by a Cooperative Iron–Thiolate Catalyst: Intermediacy of Ferrous Alkoxides in Catalytic Hydroboration

有机金属催化

环氧化物

This paper describes a cooperative iron–thiolate catalyst Cp*Fe(1,2-Ph2PC6H4S)(NCMe) (Cp*– = C5Me5–, [1(NCMe)]) for regioselective hydroboration of aryl epoxide by pinacolborane (HBpin). The critica

Figshare2017-10-13 更新20

Multiple Insertion of a Silyl Vinyl Ether by (α-Diimine)PdMe<sup>+</sup> Species

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