Azido-Directed Formation of An Unprecedented Mn(II)-Organic Framework with Nanoscale Cubic Cage Units
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A bcu topological three-dimensional Mn(II)-organic framework [Mn22(N3)8(L)12(H2O)26·5H2O]∞ (1) (L = 1,2,3-triazole-4,5-dicarboxylate) based on an unprecedented nanoscale cage has been hydrothermally synthesized. Dominating antiferromagnetic interactions were detected between the MnII ions in 1.
创建时间：
2016-02-19
