Regio- and Chemoselective Diboration of Allenes with Unsymmetrical Diboron: Formation of Vinyl and Allyl Boronic Acid Derivatives
收藏NIAID Data Ecosystem2026-03-08 收录
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A platinum-catalyzed terminal diboration of 1,1-disubstituted allenes using a differentially protected diboron is described. Diboration occurs in a regio- and chemoselective fashion to furnish vinyl and allyl boronates in good to excellent yield and selectivity. Transformation of the bis-boronyl products to other functional groups as well as in chemoselective cross-coupling is demonstrated.
创建时间：
2016-02-13
