Gold vs Rhodium Catalysis: Tuning Reactivity through Catalyst Control in the C–H Alkynylation of Isoquinolones
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https://figshare.com/articles/dataset/Gold_vs_Rhodium_Catalysis_Tuning_Reactivity_through_Catalyst_Control_in_the_C_H_Alkynylation_of_Isoquinolones/2300698
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资源简介:
A site-selective
C-4/C-8 alkynylation of isoquinolones catalyzed
by gold and rhodium complexes is reported. A broad range of synthetically
useful functional groups (−F, −Cl, −Br, −CF3, −OMe, alkyl, etc.) were tolerated, providing an efficient
and robust protocol for the synthesis either C-4- or C-8-alkynylated
isoquinolones.
创建时间:
2016-02-17



