Nickel-Catalyzed Enantioselective Addition of Styrenes to Cyclic <i>N</i>‑Sulfonyl α‑Ketiminoesters
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资源简介：
Enantioselective addition of styrenes to cyclic N-sulfonyl α-ketiminoesters was developed using the complex of Ni(ClO4)2 with chiral phosphine complex as a catalyst. A range of chiral benzofused 5-membered sultams bearing alkenylated or allylated α-tetrasubstituted amino ester framework were afforded in excellent enantioselectivities (up to 99% ee) as potential biologically active compounds for drug research.
创建时间：
2016-02-12
