Stereoselective Synthesis of 4‑Substituted Cyclic Sulfamidate-5-Phosphonates by Using Rh-Catalyzed, Asymmetric Transfer Hydrogenation with Accompanying Dynamic Kinetic Resolution
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https://figshare.com/articles/dataset/Stereoselective_Synthesis_of_4_Substituted_Cyclic_Sulfamidate_5_Phosphonates_by_Using_Rh_Catalyzed_Asymmetric_Transfer_Hydrogenation_with_Accompanying_Dynamic_Kinetic_Resolution/2134735
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资源简介：
Dynamic
kinetic resolution driven, asymmetric transfer hydrogenation
of 4-substituted cyclic sulfamidate imine-5-phosphonates produces
the corresponding cyclic sulfamidate-5-phosphonates. The process employs
a HCO2H/Et3N mixture as the hydrogen source
and the chiral Rh catalysts, (R,R)- or (S,S)-Cp*RhCl(TsDPEN), and it takes place at room temperature within
1 h with high yields and high levels of stereoselectivity.
创建时间：
2016-02-13
