An Effective Approach to Layered Structures of Hybrid Prussian Blue Complexes: Monolayered [Sm(DMF)<sub>2</sub>(H<sub>2</sub>O)<sub>3</sub>(μ-CN)<sub>3</sub>M(CN)<sub>3</sub>]<i><sub>n</sub></i>·<i>n</i>H<sub>2</sub>O and Bilayered [Sm(DMF)(H<sub>2</sub>O)<sub>3</sub>(μ-CN)<sub>4</sub>M(CN)<sub>2</sub>]<i><sub>n</sub></i>·<i>n</i>H<sub>2</sub>O (M = Fe, Co)
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数据链接：
https://figshare.com/articles/dataset/An_Effective_Approach_to_Layered_Structures_of_Hybrid_Prussian_Blue_Complexes_Monolayered_Sm_DMF_sub_2_sub_H_sub_2_sub_O_sub_3_sub_-CN_sub_3_sub_M_CN_sub_3_sub_i_sub_n_sub_i_i_n_i_H_sub_2_sub_O_and_Bilayered_Sm_DMF_H_sub_2_sub_O_sub_3_sub_-CN_sub_4_sub_M_/4008240数据链接链接失效反馈
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资源简介：
Four cyano-bridged 4f−3d (lanthanide−transition metal) bimetallic assemblies, [Sm(DMF)2(H2O)3(μ-CN)3M(CN)3]n·nH2O (M = Fe (1), Co (2)) with 2-D monolayered structures and [Sm(DMF)(H2O)3(μ-CN)4M(CN)2]n·nH2O (M = Fe (3), Co (4)) with 2-D bilayered structures (DMF = N,N-dimethylformamide), were rationally prepared by a facile approach, a ball-milling method, and characterized by X-ray diffraction studies and magnetic measurements. The unprecedented 2-D bilayered 4f−3d hexacyanometalates (3 and 4) were obtained by controllably reducing the half amount of DMF in the reactive system in comparison with 1 and 2 through a ball-milling method.
创建时间：
2016-10-12
