Borylene Insertion into Cage B–H Bond: A Route to Electron-Precise B–B Single Bond
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https://figshare.com/articles/dataset/Borylene_Insertion_into_Cage_B_H_Bond_A_Route_to_Electron-Precise_B_B_Single_Bond/5943451
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资源简介：
A new strategy to
construct electron-precise B–B single
bond via direct borylene insertion into B–H bond is described.
Reduction of bromoborylene stabilized by carborane-fused silylenes
with 2 equiv of sodium gives a new compound with a B–B single
bond. Both experimental and density functional theory results suggest
that such an electron-precise B–B single bond is formed via
in situ generated borylene insertion into B–H bond.
创建时间：
2018-03-02
