Oxidative Addition of MeI to a Rollover Complex of Platinum(II): Isolation of the Kinetic Product
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Oxidative_Addition_of_MeI_to_a_Rollover_Complex_of_Platinum_II_Isolation_of_the_Kinetic_Product/2407360
下载链接
链接失效反馈官方服务：
资源简介：
A pair of new Pt(II)/Pt(IV) 2,2′-bipyridine
cyclometalated
rollover complexes have been synthesized and characterized. [Pt(bpy-H)(CH3)(PMe3)] (1), where bpy-H = κ2N,C-2,2′-bipyridine,
was
obtained from the electron-rich precursor cis-[Pt(CH3)2(DMSO)2] with a one-pot, two step
synthesis; its reactivity has been tested with CH3I, giving
the corresponding Pt(IV) complex cis-[Pt(bpy-H)(CH3)2(I)(PMe3)] (2), which
was fully characterized. Crystals suitable for X-ray analysis were
obtained and allowed the determination of the structure of isomer 2A which is the product of the trans addition
of CH3I, usually thought of as the kinetic product.
创建时间：
2013-06-10
