Ferromagnetic Exchange in Two Dicopper(II) Complexes Using a μ-Alkoxo-μ-7-azaindolate Bridge
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https://figshare.com/articles/dataset/Ferromagnetic_Exchange_in_Two_Dicopper_II_Complexes_Using_a_Alkoxo_7_azaindolate_Bridge/3340903
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资源简介：
Syntheses, structures, and magnetic properties of two heterobridged
μ-alkoxo-μ-7-azaindolate dicopper(II) complexes, [CuII2(L−F)(μ-C7H5N2)] (1) and [CuII2(L−H)(μ-C7H5N2)]·CH3OH (2) (H3L−F = 1,3-bis(3-fluorosalicylideneamino)-2-propanol; H3L−H = 1,3-bis(salicylideneamino)-2-propanol) have been reported. Aside from
being a new type of heterobridged complex, 1 and 2 exhibit
ferromagnetic interaction (2J = 52 cm-1 for 1 and 33.4 cm-1 for
2) despite orbital complementarity (7-azaindolate HOMO is antisymmetric).
创建时间：
2016-05-07
