Enantioselective Access to Bicyclo[3.2.1]octadienone Skeleton: Total Syntheses of (+)-Engelharquinone and Its Epoxide
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https://figshare.com/articles/dataset/Enantioselective_Access_to_Bicyclo_3_2_1_octadienone_Skeleton_Total_Syntheses_of_-Engelharquinone_and_Its_Epoxide/4708651
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资源简介：
The first enantioselective
total syntheses of engelharquinone (2) and its epoxide 3 have been achieved. The
key steps include (1) catalytic asymmetric 1,4-addition of a naphthylboronic
acid derivative to a masked naphthoquinone derivative by using a chiral
Rh-complex and (2) thiolate-promoted stereospecific construction of
the bicyclo[3.2.1]octadienone scaffold.
创建时间：
2017-03-01
