Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands

Name: Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N -Donor Ligands
Creator: Taylor & Francis
Published: 2016-01-19T07:54:28+08:00

DataCite Commons2020-09-04 更新2024-07-25 收录

配位化学

晶格结构

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https://tandf.figshare.com/articles/dataset/Synthesis_and_X_Ray_Structures_of_Zinc_II_and_Cadmium_II_Heteroleptic_Complexes_Involving_1_1_Dithiolate_and_i_N_i_Donor_Ligands/1170131/1 数据链接链接失效反馈

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资源简介：

A series of zinc(II) and cadmium(II) complexes, involving a combination of S–donor (xanthates and dithiophosphates) and N-donor (1,10-phen = 1,10-phenanthroline, 2,2′–bipy = 2,2′-bipyridine) ligands, of the composition [Cd(S2COnPr)2(2,2′-bipy)] (1), [Cd(S2COnPr)2(1,10-phen)] (2), [Cd(S2P(OEt)2)2(2,2′-bipy)] (3), [Cd(S2P(OEt)2)2(1,10-phen)] (4), [Zn(S2COnPr)2(2,2′-bipy)] (5), [Zn(S2COnPr)2(1,10-phen)] (6), [Zn(S2P(OEt)2)2(2,2′-bipy)] (7), and [Zn(S2P(OEt)2)2(1,10-phen)] (8) was prepared. The complexes (1–8) were characterized by elemental analysis and single-crystal X-ray analysis. X-ray structures revealed that the coordination geometries vary from octahedral (complexes 1–4), through square-pyramidal (complexes 5 and 6) to tetrahedral (complexes 7 and 8), depending on a combination of the central metal atoms and the corresponding S-donor and N-donor ligands. Similarities and discrepancies among the individual molecular structures as well as noncovalent contacts stabilizing crystal structures are discussed in more detail.

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Taylor & Francis

创建时间：

2016-01-19