Dinuclear Zinc Catalyzed Asymmetric Spirannulation Reaction: An Umpolung Strategy for Formation of α-Alkylated-α-Hydroxyoxindoles
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https://figshare.com/articles/dataset/Dinuclear_Zinc_Catalyzed_Asymmetric_Spirannulation_Reaction_An_Umpolung_Strategy_for_Formation_of_Alkylated_Hydroxyoxindoles/2521564
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资源简介:
A highly diastereo- and enantioselective formal [3 + 2] cycloaddition of α,β-unsaturated esters and 3-hydroxyoxindoles catalyzed by a dinuclear zinc-ProPhenol complex is reported. The stereoselective Michael additions of 3-hydroxyoxindoles and the subsequent transesterifications afford spirocyclic δ-lactones.
创建时间:
2016-02-20



