Borylation of Olefin C–H Bond via Aryl to Vinyl Palladium 1,4-Migration
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The aryl to vinyl palladium 1,4-migration was realized for the first time. The generated alkenyl palladium species was trapped by diboron reagents under Miyaura borylation conditions, providing a new method to synthesize β,β-disubstituted vinylboronates. The excellent regioselectivity and broad substrate scope were observed for this novel transformation.
创建时间：
2016-03-03
