Diastereocontrolled Construction of Pactamycin’s Complex Ureido Triol Functional Array
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https://figshare.com/articles/dataset/Diastereocontrolled_Construction_of_Pactamycin_s_Complex_Ureido_Triol_Functional_Array/2518126
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An advanced intermediate in a projected synthesis of pactamycin has been prepared. Early installation of the C1-dimethylurea functionality allows for its participation in a diastereoselective, chelation-controlled addition of organometal nucleophiles to the C5 prochiral ketone. Four of the molecule’s six stereocenters are set with a ketone functional handle provided for subsequent manipulation.
创建时间：
2016-02-20
