Heterodinuclear Bridging Carbido and Phosphoniocarbyne Complexes
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
The sequential treatment of [W(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with nBuLi and [NiCl2(PEt3)2] initially affords the bridging carbido complex [WNi(μ-C)(CO)2(PEt3)2Cl{HB(pzMe2)3}], which is however unstable and isomerizes cleanly to the bridging phosphoniocarbyne complex [WNi(μ-CPEt3)(CO)2(PEt3)Cl{HB(pzMe2)3}].
创建时间：
2016-02-21
