Bifunctional Reactivity of Cu<sup>I</sup>: Sequential Ring Opening/N-Arylation
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The sequential use of a single CuI catalyst enables the one-pot synthesis of N′-arylaminooxazolidinones through a Lewis acid catalyzed rearrangement followed by an N-arylation reaction. Contrary to previous reports, the formation of a cis-fused 5,5-membered ring system occurs during the rearrangement, as proven by X-ray crystallography.
创建时间:
2009-01-01



