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Heptacoordinated Nickel(II) as an Ising-Type Anisotropic Building Unit: Illustration with a Pentanuclear [(NiL)<sub>3</sub>{W(CN)<sub>8</sub>}<sub>2</sub>] Complex

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Heptacoordinated nickel­(II) complexes characterized by substantial Ising-type single-ion anisotropy have been involved in the construction of two pentanuclear [Ni3W2] compounds by association with [W­(CN)8]3–. For one of them, slow relaxation of magnetization was observed to occur concomitantly with antiferromagnetic ordering.

创建时间:
2016-02-19
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