Highly Enantioselective Construction of Hajos–Wiechert Ketone Skeletons via an Organocatalytic Vinylogous Michael/Stetter Relay Sequence
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https://figshare.com/articles/dataset/Highly_Enantioselective_Construction_of_Hajos_Wiechert_Ketone_Skeletons_via_an_Organocatalytic_Vinylogous_Michael_Stetter_Relay_Sequence/4870286
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资源简介:
A highly
enantioselective supramolecular iminium-catalyzed vinylogous
Michael addition/Stetter relay sequence has been developed. This transformation
provided a series of Hajos–Wiechert-type fused bicyclic diones
with three continuous stereogenic centers in good yields with excellent
enantioselectivities. The obtained products can be easily transformed
into other structures with potential synthetic value.
创建时间:
2017-04-12



