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Changing the Oxothiomolybdate Ring from an Anionic to a Cationic Receptor

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https://figshare.com/articles/dataset/Changing_the_Oxothiomolybdate_Ring_from_an_Anionic_to_a_Cationic_Receptor/2975617
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The ionic recognition properties of neutral oxothiomolybdenum wheels can be changed from anionic to cationic through ionization of the internal aquo ligands. In the solid state, [Mo8O8S8(OH)10(H2O)]2- (1) interacts with two Cs+ cations to give a close supramolecular host−guest arrangement. Such interactions appear to be maintained in solution as a labile association.
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2016-02-28
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