Supramolecular Side-Chain Poly[2]pseudorotaxanes Formed by Orthogonal Coordination-Driven Self-Assembly and Crown-Ether-Based Host–Guest Interactions
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https://figshare.com/articles/dataset/Supramolecular_Side_Chain_Poly_2_pseudorotaxanes_Formed_by_Orthogonal_Coordination_Driven_Self_Assembly_and_Crown_Ether_Based_Host_Guest_Interactions/2285542
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资源简介：
The themes of coordination-driven
self-assembly, host–guest
interactions, and supramolecular polymerization are unified in an
orthogonal noninterfering fashion to deliver side-chain poly[2]pseudorotaxanes.
Specifically, a bis(p-phenylene)-34-crown-10 derivative 1 bearing two pyridyl groups polymerizes into a side-chain
poly[2]pseudorotaxane upon the addition of di-Pt(II) acceptor 4 in the presence of paraquat. Interestingly, by adding a
competitive guest 3, the poly[2]pseudorotaxane can realize
a conversion in one pot.
创建时间：
2016-02-17
