Two Large-Pore Metal–Organic Frameworks Derived from a Single Polytopic Strut
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https://figshare.com/articles/dataset/Two_Large_Pore_Metal_Organic_Frameworks_Derived_from_a_Single_Polytopic_Strut/2542594
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资源简介：
Two noninterpenetrated MOFs with strikingly different
structures, NU-108-Cu and NU-108-Zn, were
prepared from a
single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated
copper ions as nodes and is based on a 3,24 network associated with
an inherently noncatenating rht-topology. Modifications
introduced in the hexa-carboxylated struts (uniquely placed phenyl
spacers) lead to substantial changes in pore sizes, relative to those
found in other MOFs based on 3,24 networks and paddlewheel-coordinated
copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter
and octadehral Zn4O nodes in which all struts lie in a–b planes.
创建时间：
2016-02-21
