Synthesis and Structure of the First Heterodinuclear PCP−Pincer−CDP Complex with a Pd−Au d<sup>8</sup>−d<sup>10</sup> Pseudo-Closed-Shell Interaction
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The first heterodimetallic PCP pincer complex, [PdAu(Cl)2(C(dppm)2)]Cl, was prepared from [PdCl(C(dppm)2)]Cl and [AuCl(tht)]. Both metals are attached to the carbon atom of the carbodiphosphorane (CDP) functionality and are connected via a very short d8−d10 pseudo-closed-shell interaction (Pd−Au = 2.8900(3) Å) which significantly modifies the ligand backbone conformation.
创建时间：
2016-02-25
