Unexpected Reaction of Dimethyl Acetylenedicarboxylate with in Situ Generated Arylketenes Catalyzed by 1-Methylimidazole
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An unexpected 1-methylimidazole-catalyzed reaction of dimethyl acetylenedicarboxylate (DMAD) with in situ generated arylketenes leading to the synthesis of dimethyl 2-arylidenesuccinates under mild conditions is described. A plausible mechanism has been proposed.
创建时间:
2005-05-26



